Quantum Mechanics of a Particle in a Potential Well

Step 1: Understanding the Interface

When you open the simulation, you'll see three main sections:

  • Left Panel (Control Panel): Contains all adjustable parameters and controls
  • Center Area (Simulation Canvas): Displays the animated wavefunction
  • Right Panel (Info Panel): Shows procedure steps, equations, and observations

Basic Experiment

Step 2: Set Initial Parameters

  1. Set the Quantum Number (n) = 1 using the slider (this is the ground state)
  2. Keep the Box Length (L) = 5 nm for initial observation
  3. Set Wave Amplitude = 100 for clear visualization
  4. Set Animation Speed = 5x for comfortable viewing

Step 3: Start the Simulation

  1. Click the ▶ Start button to begin the simulation
  2. Observe the wavefunction oscillating in time
  3. Notice the status badge changes to "Running"
  4. Use ⏸ Pause to freeze the animation at any point

Step 4: Observe the Ground State (n = 1)

  • The wavefunction has 0 nodes (zero crossings inside the box)
  • There is 1 antinode (peak) at the center
  • Note the Energy value displayed in Live Measurements

simulation image

Fig. 1 Wave function and the Probability of the Particles trapped in 1D box.


Exploring Higher Energy States

Step 5: Increase Quantum Number

  1. Gradually increase n from 1 to 10 using the slider
  2. For each value of n, observe:
    • Number of peaks (antinodes) = n
    • Number of nodes = n - 1
    • Energy increases as n²

Step 6: Record Observations

Fill in the observation table for each quantum number:

n (Quantum Number) Energy (eV) Wavelength (nm) No. of Nodes No. of Peaks
1 0.015 10.00 0 1
2 0.060 5.00 1 2
3 0.135 3.33 2 3
4 0.241 2.50 3 4
5 0.376 2.00 4 5
6 0.542 1.67 5 6
7 0.737 1.43 6 7
8 0.963 1.25 7 8
9 1.218 1.11 8 9
10 1.504 1.00 9 10

Probability Density Analysis

Step 7: Enable Probability Display

  1. In the Display Options section, toggle ON "Show |Ψ|² (Probability)"
  2. Observe the yellow curve showing probability density as shown in fig.1
  3. Compare with the wavefunction (gradient colored curve)

Step 8: Compare Wavefunction and Probability

  • The probability density is always positive
  • Probability is zero at nodes and maximum at antinodes
  • The particle is most likely to be found at antinode positions

Box Length Investigation

Step 9: Vary Box Length

  1. Keep n = 3 constant
  2. Change Box Length (L) from 1 nm to 10 nm
  3. Observe how:
    • Wavelength changes with box length
    • Energy decreases for larger boxes
    • The same number of nodes but spread differently

Step 10: Record Box Length Effect

Box Length L (nm) Energy at n=3 (eV) Wavelength (nm)
1 3.385 0.67
3 0.376 2.00
5 0.135 3.33
7 0.069 4.67
10 0.034 6.67

Additional Features

Step 11: Use Keyboard Shortcuts

  • Press Spacebar to toggle Play/Pause
  • Press R to Reset the simulation

Step 12: Capture Screenshots

  1. Click the 📷 Capture button to save the current visualization
  2. Use these for your lab report

Step 13: Reset and Repeat

  1. Click the ↺ Reset button to return to initial state
  2. Repeat the experiment with different parameter combinations

Analysis and Conclusion

Step 14: Plot Graph

Plot graphs of:

  1. Energy (Eₙ) vs Quantum Number (n) - Should show quadratic relationship
  2. Nodes vs Quantum Number (n) - Should show linear relationship (nodes = n-1)

Step 15: Write Inferences

Based on your observations, answer:

  1. How does energy scale with quantum number?
  2. What is the relationship between n and number of nodes?
  3. How does box length affect the energy levels?
  4. Where is the particle most likely to be found for each state?

Tips for Best Results

💡 Use the Pause button to closely examine wavefunction at specific times 💡 Compare different n values side by side using screenshots 💡 Toggle probability display to understand the physical meaning 💡 Experiment with different box lengths to see confinement effects