Determination of pKa Values via Titration
Aim of the experiment
The main aim of this experiment is to determine the pKa value of a weak acid through titration with a strong base and to analyze the buffering region using a titration curve.<
The learning outcomes are mapped with the objectives
- To understand the acid dissociation constant (pKa) concept and its significance.
- Students will be able to explain the concept of acid dissociation equilibrium, define Ka and pKa, and interpret their significance in determining acid strength and behavior in buffer systems
- To perform a titration experiment and monitor pH changes.
- Students will demonstrate the ability to carry out atitration using proper laboratory technique, accurately measure pH at each stage, and record systematic data for analysis.
- To plot a titration curve and determine the buffering region.
- Students will learn to construct a titration curve (pH vs. volume of titrant), identify the buffering region, and interpret the curve’s shape in terms of acid-base equilibria.
- To calculate the pKa value using the Henderson–Hasselbalch equation.
- Students will apply the Henderson–Hasselbalch equation to calculate pKa from experimental data, particularly at the half-equivalence point, and validate theoretical predictions.
- To interpret the titration curve and compare experimental results with theoretical expectations.
- Students will critically analyze deviations between experimental and theoretical titration curves, recognize sources of experimental error, and relate observations to acid-base theory.